Product ID:FYRQUEL 220
MSDS Date:09/10/1998
FSC:9150
NIIN:00N071743
Status Code:A
MSDS Number: CJHQV

Emergency Phone: 914-693-6946

Info Phone: 800-666-1200

Cage: 01GF0

Telephone: 800-666-1200

Cage: 01GF0

PHOSPHORIC ACID, TRIPHENYL ESTER; (TRIPHENYL PHOSPHATE)

CAS: 115-86-6

RTECS: TC8400000

OSHA PEL 3 MG/M3

ACGIH TLV: 3 MG/M3

BUTYLATED TRIPHENYL PHOSPHATE MIXTURE

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 (ORAL,RAT): > 5000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPOR OR MIST MAY CAUSE
RESPIRATORY TRACT IRRITATION. TRIPHENYL PHOSPHATE MAY CAUSE
CHOLINESTERASE INHIBITION AT LEVELS ABOVE EXPOSURE LIMITS. SKIN
CONTACT MAY CAUSE MILD IRRITATION. EYE CONTACT MAY CAUSE MILD
IRRITATION. INGESTION MAY CAUSE IRRITATION OF THE GASTROINTESTINAL
SYSTEM AND DIARRHEA. INGESTION OF TRIPHENYL PHOSPHATE MAY CAUSE
CHOLINESTERASE INHIBITION. SYMPTOMS OF CHOLIN ESTERASE INHIBITION
MAY INCLUDE: HEADACHE, NAUSEA, SWEATING, NUMBNESS AND TINGLING OF
THE HANDS AND FEET, SALIVATION, MUSCLE TWITCHING, TREMORS,
INCOORDINATION, BLURRED VISION, TEARS, ABDOMINAL CRAMPS , DIARRHEA,
AND CHEST DISCOMFORT.
Effects of Overexposure:SEE HLTH HAZS. TOX INFO: A SERIES OF IN VITRO
ASSAYS (AMES TESTS, MOUSE LYMPHOMA & CHROMOSOME ABERRATION TESTS).
NO EVIDENCE OF GENETIC ACTIVITY WAS NOTED. PROD WAS TESTED IN IN
VITRO MALIGNANT TRANSF ORMATION ASSAY USING BALB/3T3 CELLS; IT DID
NOT INDUCE MORPHOLOGICAL TRANSFORMATIONS & THUS DID NOT EXHIBIT
CARCIN POTENTIAL. DAILY ADMIN OF MATL AT 100, 400/1000 MG/KG TO
RATS ON DAYS 6 THRU 20 OF GE STATION DEMONSTRATED MATERNAL TOX
(INCRD LIVER WTS & REDUCED FOOD CONSUMPTION AT HIGH-DOSE) &
FETO-TOX (REDUCTION IN FETAL BODY WT AT HIGH-DOSE) BUT NO
INDICATIONS OF TERATOGENICITY WERE OBSERVED. CON T NEHC FOR MORE
INFO .
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
NEUROMUSCULAR DISORDERS MAY BE AT AN INCREASED RISK FROM EXPOSURE
TO THIS MATERIAL.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN. SKIN: REMOVE CONTAM
CLTHG & EQUIP. THORO WASH ALL AFFECTED AREAS W/SOAP & PLENTY OF
WATER. GET M ED ATTN IF IRRIT PERSISTS. WASH CONTAM CLTHG BEFORE
REUSE. THORO CLEAN/DESTROY CONTAM SHOES. EYES: IMMED FLUSH W/PLENTY
OF RUNNING WATER FOR AT LEAST 15 MINS. REMOVE ANY CONT LENSES. HOLD
EYELIDS APAR T DURING FLUSHING TO ENSURE RINSING OF ENTIRE SURF OF
EYES & LIDS W/WATER. GET MED ATTN IF IRRIT PERSISTS. INGEST: GET
MED ATTN BY CALLING MD/POIS CTL CTR IMMED. DO NOT INDUCE VOMIT
UNLESS DIRECTED TO DO SO BY MED PERS. (SUP DAT)

Flash Point Method:PMCC
Flash Point:=246.1C, 475.F
Extinguishing Media:USE WATER FOG OR SPRAY, DRY CHEMICAL, FOAM OR
CARBON DIOXIDE EXTINGUISHING AGENTS.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . AS
IN ANY FIRE, PVNT HUMAN EXPOS TO FIRE, SMOKE, FUMES/PRODS OF
COMBUST. EVACUATE NON-ESSNTL PERS FROM FIRE AREA. IF POSS, MOVE
CONTRS FROM FIRE AREA. IF NOT LEAKING, KEEP FIRE-EXPOSED CONTRS
COOL W/WATER FOG/SPRAY TO PVNT RUPTURE DUE TO EXCESS HEAT. (STATE
REGS)
Unusual Fire/Explosion Hazard:PROD IS NOT DEFINED AS FLAM/COMBUST. IT
IS SELF-EXTING ONCE SOURCE OF IGNIT IS REMOVED. NOT SENSITIVE TO
STATIC DISCHARGE/PHYSICAL IMPACT. MAY DECOMP UNDER FIRE CNDTNS. NO
OTHER FIRE/EXPLO HAZS KNOWN . DECOMP UNDER FIRE CNDTNS CAN PRDCE
CO, PHOSPHORUS OXIDES, & ORG DECOMP PRODS.NFPA RATING: HLTH&FLAM=1,
REACTIVITY=0.

Spill Release Procedures:ISOLATE SPILL AREA & RESTRICT NON ESSNTL PERS.
ALL PERS INVOLVED IN SPILL CLEANUP SHOULD FOLLOW APPROP INDUS
HYGIENE PRACTICES. STOP SOURCE OF SPILL. DIKE AREA TO PVNT SPILL
FROM SPREADING. SOAK UP LI Q W/SUITABLE ABSORB SUCH AS CLAY,
SAWDUST/KITTY LITTER. SWEEP UP ABSORBED MATL & PLACE IN CHEM WASTE
CONTR FOR DISP. CAUTION! SPILL AREA MAY BE SLIPPERY. (OTHER INFO)

Handling and Storage Precautions:WEAR PROTECTIVE CLOTHING INCLUDING
CHEMICAL GOGGLES & RUBBER GLOVES WHEN HANDLING TO AVOID EYE & SKIN
CONTACT. AVOID INHALATION OF VAPOR/MIST. CONTAINERS SHOULD BE
LOCATED IN AREA WHERE THEY CAN BE RO TATED REGULARLY (FIRST IN,
FIRST OUT) & VISUALLY INSPECTED FOR DENTS & BULGING ON A WEEKLY
BASIS.
Other Precautions:IF BULGED DRUMS ARE FOUND, THEY SHOULD BE VENTED IN
OPEN AREA BY REMOVING TWO-INCH BUNG VERY SLOWLY. TWO-INCH BUNG
SHOULD NOT BE REMOVED COMPLETELY UNTIL THERE IS NO SOUND OF PRESS
BEING RELEASED. BUN G CAN THEN BE REMOVED BUT THIS SHOULD BE DONE
SLOWLY & W/CARE. EMPTIED CONTR MAY RETAIN PROD RESIDUE S. (SARA
REGS)

Respiratory Protection:USE NIOSH APPRVD ORG VAP/ACID GAS RESP (OVAG)
W/DUST, MIST, & FUME FILTERS TO REDUCE POTENTIAL FOR INHAL EXPOS IF
USE CNDTNS GENERATE VAP, MIST/AEROSOL & ADEQ VENT (E.G.,
OUTDOOR/WELL-VENTILATED AREA) IS NOT AVAIL. WHERE EXPOS POTENTIAL
NECESSITATES HIGHER LEVEL OF PROT, USE NIOSH APPRVD, POS-PRESS,
PRESS DEMAND, AIR-SUPP RESP. (STATE REGS)
Ventilation:AT ELEVATED PROCESSING TEMPS/IN EVENT THAT USE CNDTNS
GENERATE AIRBORNE VAP, AEROSOL/MIST, MATL SHOULD BE HANDLED IN
WELL-VENTILATED AREA.
Protective Gloves:COMBINATION NEOPRENE OVER NATURAL LATEX GLOVES ARE
RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH & DELUGE SHOWER MTG ANSI DESIGN
CRITERIA . WEAR SUITABLE PROT CLTHG & FOOTWEAR, SELECTED W/REGARD
FOR USE CNDTN EXPOS POTENTIAL. LONG SLEEVED CLTHG MAY BE USED TO
MINIMIZE SKIN CONT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRST AID PROC: IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO REDUCE RISK OF
ASPIR. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. NOTE TO MD: PROD
IS AN ORGANOPHOSPHORUS MIXT CONTAINING TRIPHENYL PHOSPHATE, A
KNOWN CHOLINESTERASE INHIBITOR IN HUMANS. IN CASES OF
CHOLINESTERASE INHIBITION, ATROPINE BY INJECTION (OTHER INFO)

Vapor Pres:0.1 MM HG @ 37.8C (100F)
Viscosity:220 SUS @ 38C (100F)
Solubility in Water:0.1 G/100 ML
Appearance and Odor:CLEAR, YELLOW LIQUID; ESSENTIALLY ODORLESS.

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG OXIDIZERS, STRONG ACIDS, STRONG BASES, AND
STRONG ALKALIS. IT HYDROLYZES SLOWLY AT AMBIENT TEMPERATURES IN
ACIDIC OR ALKALINE AQUEOUS SOLUTIONS.
Stability Condition to Avoid:PROLONGED STORAGE AT ELEVATED TEMPERATURES
(ABOVE 150F; 65.6C) SHOULD BE AVOIDED. PRODUCT IS NOT SELF-REACTIVE
AND IS NOT SENSITIVE TO STATIC DISCHARGE.
Hazardous Decomposition Products:UNDER WET ACIDIC/ALKALINE CNDTNS THIS
PROD HYDROLYZES SLOWLY & NON-VIOLENTLY TO FORM PHENOL, SUBSTITUTED
PHENOLS, & ARYL PHOSPHORIC ACIDS. VAPS MAY DECOMPOSE AT ELEVATED
TEMPS TO RELEASE HARMFUL MATLS.

Waste Disposal Methods:MATL THAT CANNOT BE USED/CHEMICALLY REPROCESSED
SHOULD BE DISPOSED OF I/A/W ALL APPLIC REGS. PROD CONTRS DESIGNED
FOR SINGLE USE SHOULD BE THORO EMPTIED BEFORE DISP. NOTE! STATE &
LOC REGS MAY BE MORE STRINGENT THAN FED. THIS PROD, IF UNUSED,
DOES NOT MEET EPA'S RCRA CRITERIA AS EITHER LISTED/CHARAC T HAZ
WASTE. (OTHER INFO)

Toxicological Information:LC50 (INHAL, RAT): > 3.1 MG/L/4H (HIGHEST
ATTAINABLE CONC); NO EFTS WERE OBSERVED. CHRONIC INHAL EFTS NOT
KNOWN. ACUTE DERMAL LD50 (RABBIT): > 2000 MG/KG (PRACTICALLY
NON-TOX). MILD SKIN IRRIT IN RABB ITS FOLLOWING 24-HR EXPOS.
CHRONIC DERMAL EFTS NOT KNOWN. HOWEVER, PRLNG &/OR RPTD CONT MAY
CAUSE IRRIT. MILD IRRIT TO RABBIT EYES. DAILY INGEST BY RATS OF
100, 400/1600 PPM OF THIS MATL IN DIET FOR 3 MONTHS PRDCED INCRS
IN LIVER & ADRENAL GLAND WTS IN FEMALES & INCRS IN LIVER WTS OF
MALES AT HIGH-DOSE LEVEL. HOWEVER, NO HISTOPATHOLOGICAL CHANGES
WERE NOTED. PROD WAS EXAMINED FOR MUTAGENIC & CLAST OGENIC ACTIVITY
IN (EFTS OF OVEREXP)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE 96 HR LC50 (RAINBOW TROUT) = > 2 MG/L. TRIARYL PHOSPHATE
ESTERS, INCL TRIPHENYL PHOSPHATE, EXHIBIT LOW AQUEOUS SOLUBILITY,
HAVE MOD POTENTIAL FOR BIOCONC & READILY UNDERGO PRIMARY & ULTIMATE
BIODE GRADATION BY NATURALLY OCCURRING MIXED-MICROBIAL POPULATIONS
PRESENT IN ACTIVATED SLUDGE & RIVER WATER. THIS PROD IS READILY
BIODEGRADABLE. HYDROLYSIS RATES FOR TRIPHENYL PHOSPHATE, A PROD
COMPONENT, ARE: AT PH 9.5: HALF-LIFE: 1.3 DAYS; AT PF 8.2:
HALF-LIFE: 7.5 DAYS; AT NEUTRAL & ACIDIC PH: TOO SLOW TO RELIABLY
MEASURE.

Transport Information:NOT REG: SURF TRANSPORT W/IN NORTH AMERICA
(U.S.A., CANADA, MEXICO) IN PACKAGES OF 119 GAL/LESS (NON-BULK).
AIR TRANSPORT W/IN NORTH AMERICA (U.S.A., CANADA, MEXICO). REG:
BULK SURF SHIPMEMTS W/IN NOR TH AMERICA (>119 GALS). WATER
TRANSPORT W/IN NORTH AMERICA (U.S.A., CANADA, MEXICO). EXPORT
SHIPMENTS (EXCLUDING NON-BULK SHIPMENTS TO CANADA & MEXICO &
SHIPMENTS VIA AIR TRANSPORT TO CANADA & MEXICO) . ENVIRON HAZ
SUBSTANCE, LIQ N.O.S. (TRIPHENYL PHOSPHATE) CLASS 9, UN 3082,
PACKING GRP III, NORTH AMERICAN EMER GUIDE # 171. PRIMARY LABEL: 9.
SUBSIDIARY RISK LABEL: MARINE POLLUTANT (TRIPHENYL PHOSP HATE, PER
49 CFR 172.101, APPENDIX B).

SARA Title III Information:OTHER PREC: FOLLOW ALL WARNINGS & PREC EVEN
AFTER CONTR IS EMPTIED. STORE AWAY FROM FOODSTUFFS/ANIMAL FEED.
CONTRS SHOULD BE STORED IN COOL, DRY, WELL-VENTILATED AREA AWAY
FROM FLAM/OXIDIZING MATLS & SOURCES OF HEAT/FLAME. EXERCISE DUE
CAUTION TO PVNT DMG TO/LEAKAGE FROM CONTR. PRLNG STOR AT ELEVATED
TEMPS UNDER WET ALKALINE/ACIDIC CNDTNS SHOULD BE AVOIDED TO ASSURE
PROD INTEGRITY. CARE SHOULD BE TAKEN TO PVNT MOISTURE CONDENSATION
IN CONTR. CARBON STEEL IS PREF MATL OF CONSTRUCTION FOR STOR
CONTRS. PROD IS NORM SHIPPED IN UNLINED TANK CARS, TRUCKS & DRUMS.
MAX STOR TEMP: 150.8F (66C). HIGHER IN ABSENCE AIR/MOISTURE. (FED
REGS)
Federal Regulatory Information:TRIPHENYL PHOSPHATE & BUTYLATED
TRIPHENYL PHOSPHATE ARE SUBJECT TO THE FOLLOWING: ENVIRON LIST:
DSL=DOMESTIC SUBSTANCE LIST-CANADA; TSCA=TOXIC SUBSTANCES CTL
ACT-LISTED. NO OTHER REG INFO IS AVAIL. WH MIS HAZ CLASS: NOT
CONTROLLED. NFPA/HMIS RATINGS: HLTH: 1; FLAM: 1; REACTIVITY: 0.
SARA REGS: AT TEMPS <4.4C (40F), VISCOSITY CHARACTS ARE SUCH THAT
IMPROVED PUMPING RATES MAY BE ACHIEVED BY WARMING. TEMPS FROM
27-37.8C (80-100F) PROVIDE GOOD RATES OF FLOW. THIS PROD CAN BE
STORED & TRANSPORTED IN E QUIP CONSTRUCTED OF MILD STEEL.
State Regulatory Information:TRIPHENYL PHOSPHATE IS SUBJECT TO THE
FOLLOWING ENVIRON LISTS: MA LIST=MASSACHUSETTS SUBSTANCE LIST; NJ
R-T-K=NEW JERSEY R-T-K HAZ SUB.; PA LIST=PENN. HAZ SUBSTANCE LIST.
FIRE FIGHT PROC: HIGH PRESS W ATER MAY SPREAD PROD FROM BROKEN
CONTRS INCREASING CONTAM/FIRE HAZ. DIKE FIRE CTL WATER FOR LATER
DISP. DO NOT ALLOW CONTAM WATER TO ENTER WATERWAYS. RESP PROT: WHEN
USING RESP CARTRIDGES/CANISTERS, T HEY MUST BE CHANGED FREQUENTLY
(FOLLOWING EACH USE/AT END OF WORKSHIFT) TO ASSURE BREAKTHROUGH
EXPOS DOES NOT OCCUR.